health Spots on my Pepper Plant

Only one plant is showing spots. What is this?
 
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I was thinking maybe water left on leaf and it got burned?
 
 
 
---Also I have not given any ferterlizers to my peppers. Should I? when? and suggestions?
 
 
 
yeah those have plenty of leaves to start giving em nutes.
spot could be from water as you suggested. could be the start of a nutrient deficiency.
 
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